Aquachloridobis(1,10-phenanthroline-κ2 N,N′)zinc(II) chloride N,N-dimethylformamide solvate
نویسندگان
چکیده
The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline mol-ecules and is bonded to one chloride ion and one water mol-ecule, resulting in a ZnN(4)ClO octa-hedral coordination environment with the Cl and O atoms in a cis conformation. The cations and anions are linked by O-H⋯Cl hydrogen bonds across a center of inversion, forming a hydrogen-bonded dimeric association. The dimethyl-formamide solvent mol-ecule is disordered over two orientations in a 0.56 (1):0.44 (1) ratio.
منابع مشابه
Aqua(3-formyl-2-oxidobenzoato-κ2 O 1,O 2)(1,10-phenanthroline-κ2 N,N′)copper(II) dimethylformamide solvate
In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O-H⋯O hydrogen bonding and inte...
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